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Illustrate the conversion between the α and β forms of d-fructose.Make sure to include the open chain form.

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Match the following. -glucose


A) a monosaccharide that is sweeter than sucrose and found in honey and fruits
B) a monosaccharide that is a component of milk sugar
C) mirror-image forms of chiral molecules
D) a carbohydrate that can be oxidized to produce an acid molecule or its corresponding anion
E) stereoisomers that are not mirror images of each other
F) a disaccharide composed of two molecules of glucose
G) a polysaccharide composed of glucose units joined by β-1,4 linkages
H) a very highly branched polysaccharide composed of glucose units
I) isomers of cyclic sugars that differ in the position of the hydroxyl group at the hemiacetal carbon atom
J) a carbohydrate composed of a large number of monosaccharides chemically combined
K) an aldopentose that is a component of nucleic acids
L) a component of starch composed of glucose units joined by a-1,4 linkages
M) a disaccharide composed of one molecule of glucose and one molecule of fructose
N) a disaccharide composed of one molecule of glucose and one molecule of galactose
O) a monosaccharide that functions as the transport form of carbohydrates in blood
P) a carbohydrate that yields two monosaccharides upon hydrolysis

Q) A) and B)
R) A) and G)

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A hemiacetal linkage consists of a


A) carbon atom bonded to both an -OH and an -OR group.
B) carbonyl group that is also bonded to a hydroxyl group.
C) carbonyl group that is also bonded to an ether linkage.
D) carbon atom bonded to two -OH groups.
E) carbon atom that is bonded to an -OR group and an -NH2 group.

F) C) and D)
G) D) and E)

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Which of the following is the correct structure for glucose 6-phosphate?


A)
Which of the following is the correct structure for glucose 6-phosphate? A)    B)    C)    D)    E) none of these
B)
Which of the following is the correct structure for glucose 6-phosphate? A)    B)    C)    D)    E) none of these
C)
Which of the following is the correct structure for glucose 6-phosphate? A)    B)    C)    D)    E) none of these
D)
Which of the following is the correct structure for glucose 6-phosphate? A)    B)    C)    D)    E) none of these
E) none of these

F) A) and B)
G) A) and D)

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A glycosidic bond is


A) a bond between any two carbohydrate molecules.
B) a bond formed between an anomeric carbon atom and any -OR group.
C) any bond that can be broken by reaction with water.
D) a bond between anomeric carbon atoms on two separate monosaccharides.
E) none of the above

F) None of the above
G) C) and D)

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Fructose can be classified as a(an)


A) aldoketose.
B) aldopentose.
C) aldohexose.
D) ketopentose.
E) ketohexose.

F) A) and C)
G) D) and E)

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Match the following. -disaccharide


A) a monosaccharide that is sweeter than sucrose and found in honey and fruits
B) a monosaccharide that is a component of milk sugar
C) mirror-image forms of chiral molecules
D) a carbohydrate that can be oxidized to produce an acid molecule or its corresponding anion
E) stereoisomers that are not mirror images of each other
F) a disaccharide composed of two molecules of glucose
G) a polysaccharide composed of glucose units joined by β-1,4 linkages
H) a very highly branched polysaccharide composed of glucose units
I) isomers of cyclic sugars that differ in the position of the hydroxyl group at the hemiacetal carbon atom
J) a carbohydrate composed of a large number of monosaccharides chemically combined
K) an aldopentose that is a component of nucleic acids
L) a component of starch composed of glucose units joined by a-1,4 linkages
M) a disaccharide composed of one molecule of glucose and one molecule of fructose
N) a disaccharide composed of one molecule of glucose and one molecule of galactose
O) a monosaccharide that functions as the transport form of carbohydrates in blood
P) a carbohydrate that yields two monosaccharides upon hydrolysis

Q) J) and N)
R) A) and E)

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All of the statements concerning monosaccharides are correct except


A) the number of stereoisomers possible is 2n,where n is the number of chiral carbon atoms in the molecule.
B) monosaccharides with 5 or 6 carbon atoms exist in solution in cyclic form.
C) the two different cyclic forms of a particular monosaccharide are called tautomers.
D) a molecule is classified as a d or l isomer by the position of the hydroxyl group on the chiral center farthest from the carbonyl group.
E) monosaccharides have the general formula Cn(H2O) n,but this only describes the number and kinds of atoms,not their structure.

F) All of the above
G) A) and C)

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Which of the following carbons in the molecule shown is a chiral carbon? Which of the following carbons in the molecule shown is a chiral carbon?   A) carbons 1 and 5 B) carbons 3 and 4 C) carbons 2,3,and 4 D) All carbons are chiral.


A) carbons 1 and 5
B) carbons 3 and 4
C) carbons 2,3,and 4
D) All carbons are chiral.

E) A) and B)
F) B) and C)

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The molecular formula of the common disaccharides in human biochemistry is


A) CH2O.
B) C2(H2O) 2.
C) C6H12O6.
D) C12H22O11.
E) C12H24O12.

F) A) and E)
G) B) and D)

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Common reducing reactions of monosaccharides are due to


A) their cyclic structures.
B) the presence of at least one hydroxyl group.
C) the presence of more than one hydroxyl group.
D) the presence of a carbonyl group,usually on the #1 carbon atom.
E) the presence of at least one chiral carbon atom.

F) B) and E)
G) A) and D)

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The disaccharide that contains a β-1,4 linkage is


A) sucrose.
B) maltose.
C) amylose.
D) lactose.

E) A) and B)
F) None of the above

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Left- and right-handed mirror image molecules are known as


A) cis-trans isomers.
B) structural isomers.
C) enantiomers.
D) anomers.
E) diastereomers.

F) D) and E)
G) A) and C)

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How many stereoisomers of an aldotetrose can exist?


A) 2
B) 4
C) 8
D) 16
E) 32

F) A) and C)
G) A) and B)

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When a monosaccharide forms a ring by interaction of one of its hydroxyl groups with its aldehyde group,the bond is referred to as a(an) ________ linkage.


A) ether
B) ester
C) acetal
D) hemiacetal
E) glycosidic

F) C) and E)
G) All of the above

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Which of the following monosaccharides is present in nucleic acids?


A) glucose
B) galactose
C) ribose
D) fructose

E) A) and B)
F) A) and C)

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Match the following. -cellulose


A) a monosaccharide that is sweeter than sucrose and found in honey and fruits
B) a monosaccharide that is a component of milk sugar
C) mirror-image forms of chiral molecules
D) a carbohydrate that can be oxidized to produce an acid molecule or its corresponding anion
E) stereoisomers that are not mirror images of each other
F) a disaccharide composed of two molecules of glucose
G) a polysaccharide composed of glucose units joined by β-1,4 linkages
H) a very highly branched polysaccharide composed of glucose units
I) isomers of cyclic sugars that differ in the position of the hydroxyl group at the hemiacetal carbon atom
J) a carbohydrate composed of a large number of monosaccharides chemically combined
K) an aldopentose that is a component of nucleic acids
L) a component of starch composed of glucose units joined by a-1,4 linkages
M) a disaccharide composed of one molecule of glucose and one molecule of fructose
N) a disaccharide composed of one molecule of glucose and one molecule of galactose
O) a monosaccharide that functions as the transport form of carbohydrates in blood
P) a carbohydrate that yields two monosaccharides upon hydrolysis

Q) A) and L)
R) A) and K)

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Starch is composed of two polymers,________,which is an unbranched chain,and ________,which is a branched polymer.


A) amylose;amylase
B) amylase;amylose
C) amylopectin;amylose
D) amylose;amylopectin
E) amylase;amylopectin

F) A) and E)
G) C) and D)

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When a cyclic acetal is formed upon the reaction of a monosaccharide and an alcohol the resulting product is called a


A) glycoside.
B) residue.
C) hemiacetal.
D) disacharide.
E) polysacharide.

F) All of the above
G) B) and E)

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Glycogen is produced by ________,and its major function is ________.


A) animals;energy storage
B) animals;as a structural component
C) plants;as a structural component
D) plants;energy storage
E) none of the above

F) C) and D)
G) B) and E)

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